PUBLICATIONS

The Tetrahydrofuran Motif in Polyketide Marine Drugs
Laura Fernández-Peña, Carlos Díez-Poza, Paula González-Andrés, Asunción Barbero

Marine Drugs 2022, Vol. 20 (2), 120

Bicyclic 5-6 Systems: Four Heteroatoms 3:1
Carlos Díez-Poza, Héctor Barbero, Laura Fernández-Peña, Asunción Barbero

Comprehensive Heterocyclic Chemistry IV, 2022, Vol. 10, pp. 395-418, Elsevier, Oxford, U.K., ISBN: 9780128186565

Influence of the Substituents on the Opening of Silylepoxy Alcohols: 5-exo-Cyclization towards Tetrahydrofurans vs. Unexpected Side Reaction Leading to Tetrahydropyrans
Carlos Díez-Poza, Asunción Barbero

Molecules 202126(23), 7386

Unexpected Domino Silyl-Prins/Aryl Migration Process from Geminal Vinylsilyl Alcohols
Carlos Díez-Poza, Asunción Barbero

Org. Lett. 2021, 23, 8385–8389

Marine Heterocyclic Compounds That Modulate Intracellular Calcium Signals: Chemistry and Synthesis Approaches
Paula González-Andrés, Laura Fernández-Peña, Carlos Díez-Poza, Carlos Villalobos, Lucía Núñez, Asunción Barbero

Marine Drugs 2021, 19 (2), 78

Intramolecular Cyclization of Alkenyl Alcohols: Towards the Synthesis of Oxacycles
Paula González-Andrés, Carlos Díez-Poza, Laura Fernández-Peña, Alberto Cherubin, Yolanda Blanco, Asunción Barbero

Chem. Proc. 2021, 3 (1),117

Organosilanes in the synthesis of saturated heterocycles 
Carlos Díez-Poza, Laura Fernández-Peña, Alberto Cherubin, Juan Lión-Villar, Asunción Barbero

Arkivoc 2020, part i, 96-116

The silyl-Prins reaction as an emerging method for synthesis of heterocycles
Carlos Díez-Poza, Héctor Barbero, Alberto Diez-Varga, Asunción Barbero

Progress in Heterocyclic Chemistry, G. Gribble and John Joule Eds., 2018, Vol. 30, pp. 13-41, Elsevier, Oxford, U.K., ISBN: 978-0-08-102788-2


Synthesis of polysusbstituted tetrahydropyrans by stereoselective hydroalkoxylation of silyl alkenols: en route to tetrahydropyranyl marine analogs
Carlos Díez-Poza, Patricia Val, Francisco J. Pulido, Asunción Barbero

Mar. Drugs 2018, 16, 421


The oxepane motif in marine drugs
Héctor Barbero, Carlos Díez-Poza, Asunción Barbero

Mar. Drugs 2017, 15, 361


Modular de novo synthesis of unsimmetrical BODYPY Dyes possessing four different aryl substituents
Natalie Netz, Carlos Díez-Poza, Asunción Barbero, Till Opatz

Eur J. Org. Chem. 2017, 4580-4599


Synthesis of O- and N-heterocycles by silyl-Prins Cyclization of Allylsilanes
Carlos Díez-Poza, Asunción Barbero

Eur. J. Org. Chem. 2017, 4651-4665


Synthesis of Azepane Derivatives by Silyl-aza-Prins Cyclization of Allylsilyl Amines: Influence of the Catalyst in the Outcome of the Reaction
Asunción Barbero, Alberto Diez-Varga, Francisco J. Pulido, Alfonso González-Ortega

Org. Lett. 2016, 18, 1972-1975


From Silylated Trishomoallylic Alcohols to Dioxaspiroundecanes or Oxocanes: Catalyst and Substitution Influence
Asunción Barbero, Alberto Diez-Varga, Francisco J. Pulido

J. Org. Chem. 2016, 81, 2704−2712


Efficient access to polysubstituted tetrahydrofurans by electrophilic cyclization of vinylsilyl alcohols
Asunción Barbero, Héctor Barbero, Alfonso González-Ortega, Francisco J. Pulido, Patricia Val, Alberto Diez-Varga, Joaquín R. Morán

RSC Advances 2015, 5, 49541-49551


Competitive Silyl–Prins Cyclization versus Tandem Sakurai–Prins Cyclization: An Interesting Substitution Effect
Alberto Diez-Varga, Héctor Barbero, Francisco J. Pulido, Alfonso González-Ortega, Asunción Barbero

Chem. Eur. J. 2014, 20, 14112-14119


Multicomponent Prins Cyclization from Allylsilyl Alcohols Leading to Dioxaspirodecanes
Francisco J. Pulido, Alberto Diez-Varga, Asunción Barbero

Org. Lett. 2013, 15, 5234-5237


Efficiency of Acid- and Mercury-Catalyzed Cyclization Reactions in the Synthesis of Tetrahydrofurans from Allylsilyl Alcohols
Francisco J. Pulido, Asunción Barbero, Patricia Val, Alberto Diez, Alfonso González-Ortega

Eur J. Org. Chem. 2012, 5350-5356


One-Pot Synthesis of 2,7-Dioxabicyclo[2.2.1]heptanes from  Oxoallylsilanes
Francisco J. Pulido, Asunción Barbero, Raquel Abad

Eur J. Org. Chem. 2011, 6974-6979


One-pot multicoupling reaction of silylcopper reagents, organolithium compounds and alpha,beta-unsaturated nitriles
Francisco J. Pulido, Asunción Barbero, Yolanda Blanco

Org. & Biomol. Chem. 2011, 9, 1454-1458


 Seven-Membered Ring Formation from Cyclopropanated Oxo- and Epoxyallylsilanes
Francisco J. Pulido, Asunción Barbero, Pilar Castreño

J. Org. Chem. 2011, 76, 5850-5855


 Synthesis of 3-Methylenecyclohexan-1-ols by Lewis Acid Catalyzed Cyclization of Epoxy-allylsilanes
Francisco J. Pulido, Asunción Barbero, Pilar Castreño

Eur J. Org. Chem. 2010, 1307-1313


Allene
Francisco J. Pulido, Pilar Castreño, Asunción Barbero

Encyclopedia of Reagents for Organic Synthesis, 2009, 1, pp. 150-155. WILEY


Silyl- and Stannylderivatives of Organocopper compounds
Francisco J. Pulido, Asunción Barbero

The Patai Series: The chemistry of Organocopper Compounds, Z. Rappoport and I. Marek Eds., Part II, Chap. 16, pp. 775-856, 2009, John Wiley & Sons, Chichester, U.K.


Pd-catalyzed cross-coupling of allylsilane-vinylcopper species with aryl and vinyl halides: the first total synthesis of (-)-nomadone
Francisco J. Pulido, Asunción Barbero, Carlos García

Tetrahedron 2009, 65, 5535-5540


Intramolecular carbonyl-ene reactions in allylsilanes
Asunción Barbero, Francisco J. Pulido, Mª Carmen Sañudo

ARKIVOC 2007, (iv), 220-233


Peterson olefination from alfa-silyl aldehydes
Francisco J. Pulido, Asunción Barbero

Nature Protocols, 2006, 1, 2068-2074


Allylstannanes and vinylstannanes from stannylcupration of C-C multiple bonds. Recent advances and applications in organic synthesis
Asunción Barbero, Francisco J. Pulido

Chem. Soc. Rev., 2005, 34, 913-920


Intramolecular ene reaction of epoxyallylsilanes: Synthesis of allyl- and vinylsilane-functionalized cyclohexanols
Asunción Barbero, Pilar Castreño, Gloria Fernandez, Francisco J. Pulido

J. Org. Chem., 2005, 70, 10747-10752


Silylcuprates from allene and their reaction with alpha,beta-unsaturated nitriles and imines. Synthesis of silylated oxo compounds leading to cyclopentane and cycloheptane ring formation
Asunción Barbero, Yolanda Blanco, Francisco J. Pulido

J. Org. Chem., 2005, 70, 6876-6883


Spiro-cyclopropanation from oxoallylsilanes
Asunción Barbero, Pilar Castreño, Francisco J. Pulido

J. Am. Chem. Soc., 2005, 127, 8022-8023


Allene: As small in size as versatile in synthesis. A general scope of its usefulness as a C-3-synthon for carbocyclic annulations Asunción Barbero, Francisco J. Pulido

Synthesis, 2004, 779-785


Allylsilanes and vinylsilanes from silylcupration of carbon-carbon multiple bonds: Scope and synthetic applications
Asunción Barbero, Francisco J. Pulido

Acc. Chem. Res., 2004, 37, 817-825


Acid-catalyzed cyclization of epoxyallylsilanes. An unusual rearrangement cyclization process
Asunción Barbero, Pilar Castreño, Francisco J. Pulido

Org. Lett., 2003, 5, 4045-4048


Addition of organometallic compounds to tin-containing cyclic ketones. Remote stereocontrol induced by the stannyl group
Asunción Barbero, Francisco J. Pulido, Juan A. Rincón

J. Am. Chem. Soc., 2003, 125, 1209-12056


A tandem allylsilane-vinylsilane difunctionalization by silylcupration of allene followed by reaction with alpha,beta-unsaturated nitriles
Asunción Barbero, Yolanda Blanco, Francisco J. Pulido

Chem. Commun., 2001, 1606-1607


Allylsilane-Vinylcopper Reagents: Palladium Mediated Coupling with Alkenyl Halides. Synthesis and [2+2] Cyclization of (+)-Ipsdienol   

Asunción Barbero, Carlos García, Francisco J. Pulido

Synlett 2001, 824-826


Allylsilane-vinylcopper reagents: Palladium-mediated coupling with alkenyl halides. Synthesis and photochemical [2+2] cyclization of (+/-)-Ipsdienol
Asunción Barbero, Carlos García, Francisco J. Pulido

Synlett 2001, 827-829


Intramolecular cyclization of tert-butyldiphenylallylsilane units and carbonyl groups: Allylsilane terminated cyclization versus the ene reaction
Asunción Barbero, Pilar Castreño, Carlos García, Francisco J. Pulido.

J. Org. Chem., 2001, 66, 7723-7728


Remote stereocontrol in carbonyl additions promoted by vinylstannanes
Asunción Barbero, Francisco J. Pulido, Juan A. Rincón, Purificación Cuadrado, Diego Galisteo, Henar Martínez-García

Angew. Chem. Int. Ed. 2001,40, 2101-2103


Functionalised allylsilanes from silylcopper reagents and allene. A useful strategy for cyclopentane annulation
Asunción Barbero, Carlos García, Francisco J. Pulido.

Tetrahedron 2000, 56, 2739-2751


Silylcupration of allenes followed by reaction with enones: A new strategy for the synthesis of methylenecyclopentanols                             

Asunción Barbero, Carlos García, Francisco J. Pulido

Tetrahedron Lett. 1999,40, 6649-6652


Stannylcupration of acetylenes followed by reaction with epoxides: A novel annulation strategy for the synthesis of cyclobutenes                

Asunción Barbero, Purificación Cuadrado, Carlos García, Francisco J. Pulido, Juan A. Rincón

J. Org. Chem. 1998, 63, 7531-7533


Stereochemical control in organic synthesis using silicon-containing compounds
Ian Fleming, Asunción Barbero, David Walter

Chem. Rev. 1997, 97, 2063-2192


In search of open-chain 1,3-sterocontrol
Asunción Barbero, David C. Blakemore, Ian Fleming, Robert N. Wesley

J. Chem. Soc., Perkin Trans. I 1997, 1329-1352


Open chain 1,3-sterocontrol
Asunción Barbero, David C. Blakemore, Ian Fleming, Robert N. Wesley

Pure Appl. Chem. 1996, 68, 585-588